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  • 1,2 Addition
  • Addition of reagents of the type X-Y to conjugated dienes in which X and Y add to adjacent doubly bonded carbons FIG
  • 1,3-Diaxial repulsion
  • Repulsive forces between axial substituents on the same side of a cyclohexane ring.
  • 1,4 Addition
  • Addition of reagents of the type X-Y to conjugated dienes in which X and Y add to the termini to diene system (see conjugated addition) FIG
  • 13C NMR
  • Nuclear magnetic resonance spectroscopy in which the environments of individual carbon atoms are examined via their mass-13 isotope.
  • 18-Electron rule
  • The number of ligands that can be attached to a transition metal are such that the sum of the electrons brought by the ligands plus the valence electrons of the metal equal 18
Department of Chemistry & Chemical Biology